Biomass: Difference between revisions
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'''Biomass''', a source of [[renewable energy]], is [[biology|biological]] material such as wood, wood waste, straw, sugar cane, algae, and many other byproducts derived from agricultural and forestry production as well as other sources. Since biomass derives from plants generated by [[solar energy]] in the [[photosynthesis]] process, it can also be defined as the biological material on [[Earth]] that has stored solar energy in the chemical bonds of the organic material. | '''Biomass''', a source of [[renewable energy]], is [[biology|biological]] material such as wood, wood waste, straw, sugar cane, algae, and many other byproducts derived from agricultural and forestry production as well as other sources. Since biomass derives from plants generated by [[solar energy]] in the [[photosynthesis]] process, it can also be defined as the biological material on [[Earth]] that has stored solar energy in the chemical bonds of the organic material. | ||
= Uses of biomass = | ==Uses of biomass== | ||
The chemical energy contained in biomass can be processed to create useable fuels. Several processes have been developed to convert biomass into various forms of fuel such as biodiesel, and ethanol. The resulting fuels can provide a cleaner alternative to | The chemical energy contained in biomass can be processed to create useable fuels. Several processes have been developed to convert biomass into various forms of fuel such as [[biodiesel]], and [[ethanol]]. The resulting fuels can provide a cleaner alternative to fossil fuels because they emit lower levels of by-products such as [[carbon monoxide]] (CO) and [[carbon dioxide]] (CO2). While there are many methods for processing biomass currently in use, the most important three are gasification, syngas cleaning/processing, and Fischer-Tropsch synthesis.<ref name=Damartzis>{{cite journal| author=T. Damartzis and A. Zabaniotou|title=Thermochemical conversion of biomass to second generation biofuels through integrated process design-A review|journal=Renewable & Sustainable Energy Reviews|volume=15|issue=1|pages=366-378|date=Jan. 2011|id=|url=}}</ref> | ||
== Biomass gasification == | == Biomass gasification == | ||
Gasification is a process of burning the biomass source at a relatively high temperature to release carbon monoxide and hydrogen. This process can occur through the use of oxygen, air, steam, or mixtures similar to these.<ref>{{cite journal| author=S. Albertazzi et al|title=The technical feasibility of biomass gasification for hydrogen production|journal=Catalysis Today|volume=106|issue=1-4|pages=297-300|date=Oct. 15, 2005|id=|url=}}</ref> When air is used to carry out the gasification process the required amount of heat is a relatively low to medium heating value. This process requires less thermal energy to complete but creates higher levels of unwanted by-products such as methanol and less of the useable hydrogen product. The use of steam requires a higher amount of thermal energy to carry out the process but will yield higher amounts of actual hydrogen and lower amounts of by-products. Gasification involves four main steps, drying, pyrolysis | Gasification is a process of burning the biomass source at a relatively high temperature to release carbon monoxide and [[hydrogen]]. This process can occur through the use of [[oxygen]], [[air]], [[steam]], or mixtures similar to these.<ref>{{cite journal| author=S. Albertazzi et al|title=The technical feasibility of biomass gasification for hydrogen production|journal=Catalysis Today|volume=106|issue=1-4|pages=297-300|date=Oct. 15, 2005|id=|url=}}</ref> When air is used to carry out the gasification process the required amount of [[heat]] is a relatively low to medium heating value. This process requires less thermal energy to complete but creates higher levels of unwanted by-products such as [[methanol]] and less of the useable hydrogen product. The use of steam requires a higher amount of thermal energy to carry out the process but will yield higher amounts of actual hydrogen and lower amounts of by-products. Gasification involves four main steps, drying, [[pyrolysis]], [[reduction]] and [[combustion]]. The drying process consists of taking the biomass source and removing all the moisture. After the moisture is removed the resulting substance enters the pyrolysis zone. This is where [[Volatility (chemistry)|volatiles]] are removed in the form of carbon monoxide and carbon dioxide and also where tar is produced. After this process occurs the resulting substance goes over to the reduction zone where the raw materials are completely gasified in order to create a syngas product. Finally in the combustion zone the left-over char material is burned which produces more gaseous product and also produces the necessary heat for the reactions in the previously mentioned reduction zone. The end product is known as syngas. Syngas can be used as a fuel or it can be further processed to create [[synthetic natural gas]] (SNG) or synthetic [[Petroleum crude oil|petroleum]]. | ||
== Syngas purification == | == Syngas purification == | ||
When syngas is used for further processing it undergoes a cleaning and purification stage. The gas cleaning stage is the first stage of syngas purification. This process involves the use of mechanical filters which remove particulate matter, and | When syngas is used for further processing it undergoes a cleaning and purification stage. The gas cleaning stage is the first stage of syngas purification. This process involves the use of mechanical filters which remove [[particulate matter]], and [[Adsorption|adsorbents]] that remove the [[alkali]] and [[sulfur]] compounds in the gas. The remaining tar in the gas is then broken down through the use of [[catalysis]] and steam.<ref name=Damartzis/> Syngas cleaning is a crucial step in preventing the fouling of machinery or contamination of catalysts when further processing the gas. | ||
== Fischer-Tropsch synthesis == | == Fischer-Tropsch synthesis == | ||
The last commonly used stage of processing biomass is known as Fischer-Tropsch synthesis. Purified syngas will be | The last commonly used stage of processing biomass is known as Fischer-Tropsch synthesis. Purified syngas will be processede through a series of catalytic steps which will eventually transform the gas into a liquid fuel.<Ref name=Damartzis/> This fuel can be used in standard piston engines and can substitute for the use of fossil fuels. This process requires substantial thermal energy to carry out and is a relatively costly process. Efforts have been made to reduce the costs of this process to make it a reasonable competitor to the processing of oil for the creation of petroleum based fuels. | ||
=Risks of biomass processing= | ==Risks of biomass processing== | ||
The risk level of biomass processing depends largely on the inspection and maintenance standards of the processing facility. From 2006 to 2010 there have been approximately 100 incidents in the United States regarding the processing of biomass | The risk level of biomass processing depends largely on the inspection and maintenance standards of the processing facility. From 2006 to 2010 there have been approximately 100 incidents in the United States regarding the processing of biomass to produce biofuels. From 2006 to 2009 there have been 8 fires and 6 explosions on the basis of about 200 biodiesel facilities. Some of these explosions were responsible for the complete destruction of their respective plants. However, 50% of the incidental cases in the last 5 years have not involved the process under normal conditions and 22 % of the incidents have been related to tank storage (overfilling, leaks, etc.).<ref>{{cite journal| author=E. Salzano, M. Di Serio and E. Santacesaria|title=Emerging Risks in the Biodiesel Production by Transesterification of Virgin and Renewable Oils|journal=Energy & Fuels|volume=24|issue=| pages=6103-6109|date=Nov. 2010|id=|url=}}</ref> Given that maintenance is properly carried out, incidents such as these will rarely occur. The unstable nature of the materials in addition to the poor plant regulation is the reason why incidents are so frequent. As a result, improvement efforts on regulation, inspection, and maintenance of the processing plants have been carried out with the goal of drastically reducing the number of incidents. | ||
=Setbacks and the future of biomass= | ==Setbacks and the future of biomass== | ||
The cost of collecting and processing biomass is the current main concern for the energy and transportation industries. Efforts are being made to expand the production and distribution of these fuels in order to lower costs to the consumer. However, costs of biofuels are still far higher than the costs of petroleum based fuels. The environmental availability of biomass is not an issue because sources such as food waste and other forms of waste are constantly being renewed. As prices for petroleum based fuels continue to rise and more efficient technologies for processing biomass are developed, demand for these alternative fuels will begin to increase considerably. As a result, biomass may very well be the alternative fuel source of choice for the immediate future. | The cost of collecting and processing biomass is the current main concern for the energy and transportation industries. Efforts are being made to expand the production and distribution of these fuels in order to lower costs to the consumer. However, costs of biofuels are still far higher than the costs of petroleum based fuels. The environmental availability of biomass is not an issue because sources such as food waste and other forms of waste are constantly being renewed. As prices for petroleum based fuels continue to rise and more efficient technologies for processing biomass are developed, demand for these alternative fuels will begin to increase considerably. As a result, biomass may very well be the alternative fuel source of choice for the immediate future. | ||
=References= | ==References== | ||
{{reflist}} | {{reflist}} | ||
Revision as of 16:01, 24 March 2011
Biomass, a source of renewable energy, is biological material such as wood, wood waste, straw, sugar cane, algae, and many other byproducts derived from agricultural and forestry production as well as other sources. Since biomass derives from plants generated by solar energy in the photosynthesis process, it can also be defined as the biological material on Earth that has stored solar energy in the chemical bonds of the organic material.
Uses of biomass
The chemical energy contained in biomass can be processed to create useable fuels. Several processes have been developed to convert biomass into various forms of fuel such as biodiesel, and ethanol. The resulting fuels can provide a cleaner alternative to fossil fuels because they emit lower levels of by-products such as carbon monoxide (CO) and carbon dioxide (CO2). While there are many methods for processing biomass currently in use, the most important three are gasification, syngas cleaning/processing, and Fischer-Tropsch synthesis.[1]
Biomass gasification
Gasification is a process of burning the biomass source at a relatively high temperature to release carbon monoxide and hydrogen. This process can occur through the use of oxygen, air, steam, or mixtures similar to these.[2] When air is used to carry out the gasification process the required amount of heat is a relatively low to medium heating value. This process requires less thermal energy to complete but creates higher levels of unwanted by-products such as methanol and less of the useable hydrogen product. The use of steam requires a higher amount of thermal energy to carry out the process but will yield higher amounts of actual hydrogen and lower amounts of by-products. Gasification involves four main steps, drying, pyrolysis, reduction and combustion. The drying process consists of taking the biomass source and removing all the moisture. After the moisture is removed the resulting substance enters the pyrolysis zone. This is where volatiles are removed in the form of carbon monoxide and carbon dioxide and also where tar is produced. After this process occurs the resulting substance goes over to the reduction zone where the raw materials are completely gasified in order to create a syngas product. Finally in the combustion zone the left-over char material is burned which produces more gaseous product and also produces the necessary heat for the reactions in the previously mentioned reduction zone. The end product is known as syngas. Syngas can be used as a fuel or it can be further processed to create synthetic natural gas (SNG) or synthetic petroleum.
Syngas purification
When syngas is used for further processing it undergoes a cleaning and purification stage. The gas cleaning stage is the first stage of syngas purification. This process involves the use of mechanical filters which remove particulate matter, and adsorbents that remove the alkali and sulfur compounds in the gas. The remaining tar in the gas is then broken down through the use of catalysis and steam.[1] Syngas cleaning is a crucial step in preventing the fouling of machinery or contamination of catalysts when further processing the gas.
Fischer-Tropsch synthesis
The last commonly used stage of processing biomass is known as Fischer-Tropsch synthesis. Purified syngas will be processede through a series of catalytic steps which will eventually transform the gas into a liquid fuel.[1] This fuel can be used in standard piston engines and can substitute for the use of fossil fuels. This process requires substantial thermal energy to carry out and is a relatively costly process. Efforts have been made to reduce the costs of this process to make it a reasonable competitor to the processing of oil for the creation of petroleum based fuels.
Risks of biomass processing
The risk level of biomass processing depends largely on the inspection and maintenance standards of the processing facility. From 2006 to 2010 there have been approximately 100 incidents in the United States regarding the processing of biomass to produce biofuels. From 2006 to 2009 there have been 8 fires and 6 explosions on the basis of about 200 biodiesel facilities. Some of these explosions were responsible for the complete destruction of their respective plants. However, 50% of the incidental cases in the last 5 years have not involved the process under normal conditions and 22 % of the incidents have been related to tank storage (overfilling, leaks, etc.).[3] Given that maintenance is properly carried out, incidents such as these will rarely occur. The unstable nature of the materials in addition to the poor plant regulation is the reason why incidents are so frequent. As a result, improvement efforts on regulation, inspection, and maintenance of the processing plants have been carried out with the goal of drastically reducing the number of incidents.
Setbacks and the future of biomass
The cost of collecting and processing biomass is the current main concern for the energy and transportation industries. Efforts are being made to expand the production and distribution of these fuels in order to lower costs to the consumer. However, costs of biofuels are still far higher than the costs of petroleum based fuels. The environmental availability of biomass is not an issue because sources such as food waste and other forms of waste are constantly being renewed. As prices for petroleum based fuels continue to rise and more efficient technologies for processing biomass are developed, demand for these alternative fuels will begin to increase considerably. As a result, biomass may very well be the alternative fuel source of choice for the immediate future.
References
- ↑ 1.0 1.1 1.2 T. Damartzis and A. Zabaniotou (Jan. 2011). "Thermochemical conversion of biomass to second generation biofuels through integrated process design-A review". Renewable & Sustainable Energy Reviews 15 (1): 366-378.
- ↑ S. Albertazzi et al (Oct. 15, 2005). "The technical feasibility of biomass gasification for hydrogen production". Catalysis Today 106 (1-4): 297-300.
- ↑ E. Salzano, M. Di Serio and E. Santacesaria (Nov. 2010). "Emerging Risks in the Biodiesel Production by Transesterification of Virgin and Renewable Oils". Energy & Fuels 24: 6103-6109.